I think the clip you've seen is "The Web of Fear" where they find the man covered in webbing. He's behind or next to a sliding metal gate as is often used in elevators, or in this at the top of the steps leading out of the Tube to the surface of London.
Not sure if this is from Episode 1, a censor clip from the other episodes, or a "recreated" scene done especially for "30 Year on the TARDIS".